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Content material: Foreword, web page ixAbbreviations and emblems, Pages x-xiIntroduction, Pages 1-4II - Graphical abstracts of response numbers, Pages 5-21RXN1 - Cross-Coupling of Organometallics with RX Derivatives, Pages 23-47RXN2 - Cross-Coupling of Organometallics with RCOX Derivatives, Pages 48-52RXN3 - Cross-Coupling of Siloxycyclopropanes with RX and RCOX Derivatives, Pages 53-54RXN4 - Cross-Coupling of Terminal Alkynes with RX Derivatives, Pages 55-60RXN5 - Intermolecular HECK response, Pages 61-71RXN6 - Intramolecular HECK response, Pages 72-79RXN7 - Intramolecular Coupling of Di(Vinyl Halides), Pages 80-81RXN8 - Tandem HECK-Anion trap technique of Alkenes, Alkynes, Allenes and Dienes, Pages 82-85RXN9 - Tandem HECK-Anion catch means of Norbornene and similar Compounds, Pages 86-88RXN10 - Tandem Arylsulfonation-Cyclization technique, Pages 89-90RXN11 - Tandem Cyclization-Anion seize (-Carbonylation) means of Alkenes, Allenes and Alkynes, Pages 91-94RXN12 - Tandem Cyclization-Anion-Capture means of Ene-Vinyl, Ene-Aryl and Ene-Alkyl Halides, Pages 95-98RXN13 - 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Telomerization of 1,3-Dienes with Nucleophiles, Pages 228-231RXN56 - WACKER strategy, Pages 232-234RXN57 - education of Ketones from Alcohols or Derivatives through a β-Hydride removal, Pages 235-237RXN58 - instruction of α,β-Unsaturated Carbonyl Derivatives through a β-Hydride removal, Pages 238-240RXN59 - practise of α-Diketones Derivatives through an Oxidative Rearrangement of a Propargyl Acetate, Pages 241-242RXN60 - Carbonylation, Pages 243-252RXN61 - Isomerization of Alkynes, Pages 253-255RXN62 - Addition of Thiols to Alkynes, Pages 256-257RXN63 - practise of Allylic Acetates from Alkynes by means of Tandem Redox-Addition, Pages 258-259RNX64 - Tandem Cyclization-Capture means of Enynes, Pages 260-261RXN65 - Aldol-Like Condensation of Enol Esters with Aldehydes, Pages 262-263RXN66 - Addition of Fluoroalkyl lodides to Alkenes or Alkynes through a Pd(I) Species, Pages 264-265RXN67 - Intermolecular Tandem Carbonylation-Coupling-Cyclization strategy of Aryl Halides with Terminal Alkynes, Pages 266-267RXN68 - 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Additional resources for A Critical Review of Equilibrium Data for Proton and Metal Complexes of 1,10–phenanthroline, 2,2'–Bipyridyl and Related Compounds. Critical Evaluation of Equilibrium Constants in Solution: Stability Constants of Metal Complexes

Example text

85 17 - 11 500 Rej 59G Rej 62Aa 62C 11 11 61J 16 25 0 . 95 25 0 . 56 12, 20 0 . 08 1 4 b ,16 18a 621 13 18 14b 18b KiDt 62C 63A Ln O "· « ON Kj 03 Ln Ln o o> Ηί o CU o o jl)o (1)o (1)n (D (D hO hO hO hO hO ON ON ON ON ON ON CO ON ho U) « > > ON Ln ON hO M 62 f Ln Ln O si Ln Ln ON H< «vj I— ' -P>» CO Lo CO h-1 CO CO Ln hO H Ln Ln O N O WI U H si O si V O 0 > L n O > c o 4 > - ^ J C O - P ^ O^ UJ hO LO Ln Ln O h O C O C o C O - F» -^ 00 CO Ln 00 Ln H» H» o N> Ln ho 0> H CO VO Co Co Co Co 4>» m si sj oo o Ln co en o hO Ln o hO Ln CO LO Ln Ln hO ON J> 4>.

10 - 50% aq. 43 25 50% aq. 65 25 50% aq. 80 25 50% aq. 23 50% aq. 13 25 25% aq. MeOH 50% aq. MeOH 75% aq. 73 25 25% aq. EtOH 50% aq. EtOH 75% aq. l (Continued) Substituent Unsubstituted pKi Method Reference 25 25% aq. n-PrOH 50% aq. n-PrOH 75% aq. 58 25 25% aq. Me 2 CO 50% aq. M e 2 C 0 75% aq. 2 7 ON 25 25 25 25 25 25 25 25 25 25 Aq. 001 I 8% aq. 4% aq. 3% aq. 4% aq. 0% aq. 1% aq. 7% aq. 0% aq. 6% aq. 2 Temp. PKi Temp. 34 20 20% aq. 62 25 50% aq. 47 25 50% aq. 41 25 50% aq. 58 25 50% aq. 94 25 75% aq.

3 Pi - 1 7 . 5 11 59G 23i - 1 0 . 1 (Continued) Auxiliary Ligand A Metal Complex log K log ß log X Medium Temp. 64 Temp. 87 Dt NN Bis(carboxymethyl)dithiocarbamate Cu(II) MLA Toluene-3,4-Dithiol Zn(II) Pyrocatechol violet - log ß log X Medium Temp. Method 25 12 12 720 ? 1 KC1 25 12 720 ? 12 72Ga ? 1 KC1 ? 89 Dt - ? 1 KNO3 ? 2 Equilibrium Constants of Mixed Complexes 2,2f-Bipyridyl = L Auxiliary Ligand A Hydroxide Metal Complex Fe(III) M2(0H)2L4 Cu(II) MOHL log K log ß M 2 (0H) 2 L 2 Temp. Method Reference var.

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